Structure of Mixed-Anions Tris(2-pyridylmethyl)amine Mn Complex, TPAMn(η-NO3)(η-ClO4)
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چکیده
Mononuclear mixed-anions Mn complex of TPAMn(η-NO3)(η-ClO4), where TPA is tris(2-pyridylmethyl)amine, has been synthesized and characterized. The neutral TPAMn(η-NO3)(η-ClO4) was obtained from the reaction between Mn(NO3)2·4H2O and [H3TPA](ClO4)3 in MeOH. X-ray crystallographic structure of mononuclear TPAMn(η-NO3)(η-ClO4) complex showed a seven-coordinated geometry with a tripodal tetradentate TPA, a terminal perchlorate and an η-bound nitrate.
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